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Nanoparticle deposition
SourceAt Mantis Deposition we offer a
complementary range of instruments for the deposition and
characterisation of nanoparticles. Our instruments allow precise
beams of size-selected nanoparticles to be generated from almost
any elemental or alloy base material. In addition, reactive
particle generation allows oxide or nitride compound nanoclusters
to be deposited. We can offer instruments for retrofit to existing
vacuum chambers or complete system solutions for nanoparticle film
growth.
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The Nanogen-50 nanocluster source
uses a unique high-pressure sputtering source to generate
nanoparticles within a condensation zone. The gas flow
characteristics within the condensation zone ensures refinement of
the size distribution of the beam to allow precise definition of
the particle size in the emergent beam. The unique configuration
of the condensation zone also maximises the ratio of nanoparticle
to carrier gas entering the main deposition chamber. The source
can be supplied with user-selectable refinement zones to suit
particular applications. Nanoparticles can be generated with as
few as 30 atoms up to those with diameters exceeding 15nm.
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Soft-landing vs accelerated impact
The
Nanogen source produces a high percentage of ionised nanoparticles
(up to 40%). Under normal running conditions, the particles, both
neutral and ionised, emerge from the source with very low kinetic
energy. This ensures that particles subsequently deposited on
surfaces are 'soft-landed' and retain their nanocrystalline
structure. Alternatively, the high degree of ionisation allows
users to manipulate a large fraction of the particle beam
electrostatically. It is possible to accelerate the ionised
particles to a biased surface, for example, in order to impact the
particles on the surface with elevated kinetic energy allowing
partial or total interface mixing between the substrate and the
particulate beam. Such accelerated beams can be used to create
highly adherent films on difficult materials such as untreated
Teflon or glass at room temperature.

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The
MesoQ quadrupole mass filter can be used in-line with
the NanoGen-50 to analyse and further filter the
nanoparticle beam with throughput up to 10^6 amu. The
quadruople has an ultimate size resolution of better
than 2% in filtering mode, allowing precise particle
size definition to be achieved. When used in conjunction
with the Nanogen source, the MesoQ allows
high-throughput in filter mode as a high proportion of
the beam is naturally ionised. In conventional quarupole
devices, the gases to be analysed must first be ionised
prior to entry into the filter. The MesoQ is supplied as
standard with software control for analysis from a
Windows-based PC.
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Mantis Deposition offers a
complete nanoparticle deposition solution in the shape of a UHV-compatible
deposition system. Users can either choose the standard
configuration or customise the system according to their specific
needs. At the heart of the system lies the NanoGen nanoparticle
deposition source (see above) and the source positioning and
ancillary chamber components have been specifically designed the
maximise the operation of this source. The standard sample
manipulator features sample heating, bias and rotation for 2 inch
samples. Numerous ports are available for additional deposition
sources to allow, for example, matrix encapsulation of
nanoparticles for thin-film structures or devices as well as for
viewports and optional sample-entry load-lock systems. |
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